CHEMISTRY
Room 210, J.M. Smith Building

PETER K. BRIDSON, PhD
Chair

ROGER V. LLOYD, PhD
Coordinator of Graduate Studies
(901)-678-2632
E-mail: rlloyd@memphis.edu
www.chem.memphis.edu

I. The Department of Chemistry offers graduate programs leading to the Master of Science and Doctor of Philosophy degrees with a major in chemistry. Concentrations are available in analytical, computational, inorganic, organic, and physical chemistry. Related courses may be taken in other departments including physics, mathematics, geology, biology, and engineering and in fields other than the student’s major within the Department of Chemistry.

II. MS Degree Program

Program objectives are: (1) competence in a common core of material in the major area of specialization; (2) experience in experimental design, data analysis, and oral and written presentation of research results; (3) competitive for professional positions in the chemical sciences.

A. Program Admission and Prerequisites

Prospective students, in addition to meeting the requirements for admission to The Graduate School, are required to present as a prerequisite for admission a satisfactory record of undergraduate work in chemistry; normally 32 semester hours of chemistry will be required, including quantitative analysis, organic, and physical chemistry. Students who are deficient in undergraduate work may be admitted and the deficiencies removed without graduate credit. Submission of GRE scores is required for admission, but permission for a waiver may be requested from the department for extraordinary circumstances.

B. Program Requirements

  1. Diagnostic Examinations—Before registering for the first time, incoming graduate students will take a series of standardized examinations, one each in inorganic, analytical, organic, and physical chemistry. The examinations are at a level equivalent to completion of the following undergraduate courses at the University of Memphis: CHEM 4111 (inorganic), 4211 (analytical), 4311 (organic), and 4411 (physical). A candidate for the Master of Science degree must make at least 50th percentile on three of these tests or take the equivalent classes (CHEM 6111, 6211, 6311, 6411). Students should note that a score of 75th percentile on the test or a "B" or better in the course is prerequisite to higher level graduate courses in each area.
  2. Course Work Requirements—The thirty semester-hour total required is subject to the following restrictions:
    1. No more than nine hours of credit at the 6000 level may be counted towards the Master of Science degree. At least nine hours must be in courses numbered CHEM 7100-7899, with at least two areas of chemistry represented.
    2. A maximum of six semester hours of Chemistry 7996 (Thesis) can be applied to the thirty semester-hour requirement.
    3. A maximum of three semester hours of CHEM 7910/8910 (Special Problems in Chemistry) may be counted toward the thirty semester-hour requirement.
    4. Presentation (CHEM 7911) is required of all graduate students. A maximum of four semester-hours from some combination of CHEM 7911, and 7/8913 (Seminar) may be used to meet the thirty semester-hours required.
    5. A maximum of six semester-hours credit can be granted for graduate courses successfully completed at other accredited institutions. Credit previously earned at another institution must be presented for evaluation not later than the end of the student’s second semester of enrollment.
    6. No more than six semester-hours of CHEM 7001 (Directed Research) and CHEM 7996 (Thesis) combined may be counted toward the thirty semester-hour requirement.
  3. Comprehensive Examinations—The student must begin the written part of the comprehensive examinations by the beginning of the third semester and take up to eight consecutive tests. These are described in the summary of the administration of the graduate program. A student pursuing the master’s degree must obtain a total of at least six points. Any student who has not amassed six points at the completion of eight tests is automatically terminated from the Master’s degree program. Written permission from the student’s advisory committee is required to delay beginning the tests or to delay continuing once the student has begun taking tests. Within six months of obtaining the required six points, students must complete the oral part of the comprehensive examinations. The student will prepare a Research Prospectus on his or her thesis research problem, to be presented orally to the Advisory Committee in an open meeting and in a written form to the Graduate Studies Committee. The oral comprehensive examination can be repeated.
  4. Seminar—Participation in seminar is required during each semester of residence (excluding summer terms).
  5. The Advisory Committee—Upon admission to the Graduate School, the student will be advised by the Department’s Graduate Studies Committee. A student must choose a major professor before the end of the second semester following enrollment. The major professor, in consultation with the student, will recommend to the department chair faculty members to be appointed to the student’s advisory committee. This committee, which is appointed as soon as the student has selected a major professor, must be composed of at least three members, with the major professor serving as chair. Upon appointment, the committee will review the student’s progress to date and outline an appropriate program tailored to the student’s individual interests to permit fulfillment of the degree requirements.
  6. Thesis Option—Each student must submit a thesis acceptable to the student’s advisory committee. The thesis can be based on work done for CHEM 7996, for which a maximum of six credit-hours can be applied to the degree requirement.
  7. Non-Thesis Option—If a non-thesis program is selected, a student must prepare a detailed report in the form of a review or proposal, based on literature research. Three hours credit for CHEM 7910 will be earned.
  8. Final Oral Examination—A final oral examination on the student’s thesis or report and related material will be administered by the student’s advisory committee after completion of all other requirements. This examination will be held seven or more days after the student has distributed copies of the thesis or report to the members of the advisory committee, which must be done at least one month before the end of the semester in which the student expects to graduate. If the final oral examination is unsatisfactory it must be repeated within one year; it may not be repeated more than once.
  9. Retention—A student pursuing the Master’s degree program may be terminated for any of the following reasons:
    1. Failure to maintain a grade point average of 3.0 or above. A student who has a cumulative grade point average below 3.0 will be placed on probation. Continuation in graduate school must be approved by the Assistant Vice Provost for Graduate Studies. Any person whose continuation is denied may appeal the decision to the University Council for Graduate Studies and Research.
    2. Failure to accumulate the requisite number of points on the departmental comprehensive examinations (See Section 3).
    3. Failure to complete the degree requirements within six years of initial enrollment in the graduate program.
    4. Failure to satisfy the advisory committee on the final oral examination (See Section 8).

III. PhD Degree Program

Program objectives are: (1) competence in a common core of material in the major area of specialization; (2) proficiency in a minor area of specialization outside of the major; (3) development of expertise in experimental design, data analysis, and oral and written presentation of research results; (4) competitive for professional positions in the chemical sciences.

A. Program Admission

See MS admission requirements.

B. Program Requirements

  1. Diagnostic Examinations—Before registering for the first time, incoming graduate students will take a series of standardized examinations, one each in inorganic, analytical, organic, and physical chemistry. The examinations are at a level equivalent to completion of the following undergraduate courses at The University of Memphis: CHEM 4111 (inorganic), 4211 (analytical), 4311 (organic), and 4411 (physical). A doctoral candidate must make at least 50th percentile on all of these tests or take the equivalent classes (CHEM 6111, 6211, 6311, 6411). Students should note that a score of 75th percentile on the test or a "B" or better in the course is prerequisite to higher level graduate courses in each area.
  2. Course Work Requirements—The doctoral degree program includes the requirement of the satisfactory completion of a minimum of 72 semester hours of graduate credit beyond the BS degree. The 72-hour total is subject to the following restrictions:
    1. No more than fifteen hours of credit at the 6000 level may be counted towards the doctoral degree. At least twelve hours must be in courses numbered CHEM 7100-7899 (8100-8899), with at least two areas of chemistry represented.
    2. A maximum of 30 hours credit for CHEM 8001 (Directed Research) and CHEM 9000 (Dissertation) combined can be applied toward the 72-hour total.
    3. A maximum of 12 hours of CHEM 7/8910 (Special Problems in Chemistry) may be credited toward the total hour requirement.
    4. A maximum of 12 hours of course work may be included in a field related to chemistry (physical or biological sciences, mathematical sciences, or engineering). Courses taken in related areas must be numbered 6000 or above.
    5. Presentation (CHEM 7911) and Advanced Presentation (CHEM 8911) are required. A maximum of four semester-hours from some combination of CHEM 7911, 8911, and 7/8913 may be used to meet the 72 semester-hour requirement.
    6. A maximum of 30 hours of graduate course credit completed at the University or other accredited institution (including credit applied on an MS degree) may be applied to the 72-hour requirement subject to the approval of the student’s advisory committee and the Department’s Graduate Studies Committee. A minimum of 18 hours in graduate courses other than CHEM 7/8910, CHEM 7/8913, and CHEM 8001/9000 must be completed at the university.
  3. Residence—Of the total semester-hour requirement, a minimum of 24 hours must be earned while the student is at The University of Memphis. This requirement cannot be met wholly by attendance at Summer Sessions, and must include at least one academic year of full-time student status.
  4. Comprehensive Examinations—The student must begin the written part of the comprehensive examinations by the beginning of the third semester and take up to eight consecutive tests. These are described in the summary of the administration of the graduate program. A student pursuing the doctoral degree must obtain a total of at least twelve points. Any student who has not amassed twelve points at the completion of eight tests is automatically terminated from the doctoral degree program. Written permission from the student’s advisory committee is required to delay beginning the tests or to delay continuing once the student has begun taking tests. Within six months of obtaining the required twelve points, students must complete the oral part of the comprehensive examinations. The student will prepare a Research Prospectus on his or her thesis research problem, to be presented orally to the Advisory Committee in an open meeting and in a written form to the Graduate Studies Committee. The oral comprehensive examination can be repeated. A student who changes major professors must present a new Research Prospectus within one semester after the change is made.
  5. Students who enter the PhD program and already hold the MS degree in chemistry must begin taking the cumulative examinations at the first opportunity after initial enrollment if a satisfactory score is made on the diagnostic examinations.
  6. Seminar—Participation in Seminar is required during each semester of residence (excluding summer terms).
  7. The Advisory Committee—Upon admission to the Graduate School, the student will be advised by the Department’s Graduate Studies Committee. A student must choose a major professor from the graduate faculty before the end of the second semester following enrollment. The major professor, in consultation with the student, will recommend to the department chair faculty members to be appointed to the student’s advisory committee. This committee, which is appointed as soon as the student has selected a major professor, must be composed of at least five members, with the major professor serving as chair. Of the members of this committee, at least one is to be from a different area of specialization from that in which the student intends to work. Upon appointment, the committee will review the student’s progress to date and outline an appropriate program tailored to the student’s interests to enable fulfillment of the degree requirements.
  8. A student who enters the PhD program and already holds the MS degree in chemistry must select a major professor during the first semester in residence, or upon completion of the diagnostic examinations.

    In the event that a student changes major professors, a new advisory committee must be appointed.

  9. Admission to Candidacy—In order to apply for candidacy, the student must have an advisory committee and must have successfully completed the departmental comprehensive examination requirement. The written and oral portions of the comprehensive examinations (the oral exam replaces the research prospectus) collectively satisfy the comprehensive examination requirement of the Graduate School. The test scores, transcripts, and other pertinent data will be examined by the student’s advisory committee, and their recommendation, with the approval of the department chair, will be forwarded to the Graduate School.
  10. Doctoral Research and Dissertation—Registration for nine semester hours of CHEM 9000 and CHEM 8001 combined is required of all doctoral candidates before the dissertation will be considered.
  11. Final Examination—The student’s advisory committee will administer a final oral examination on the student’s dissertation and related material after completion of all course requirements and the dissertation. This examination will be held two weeks or more after the student has distributed copies of the dissertation to the members of the advisory committee; which must be done at least five weeks before the end of the semester in which the student expects to graduate. If the final oral examination is unsatisfactory, it must be repeated within one year. It may not be repeated more than once.
  12. Retention—A student pursuing the doctoral degree program may be terminated for any of the following reasons:
    1. Failure to maintain a grade point average of 3.0 or above. A student who has a cumulative grade point average below 3.0 will be placed on probation. The Assistant Vice Provost for Graduate Studies must approve continuation in graduate school. Any person whose continuation is denied may appeal the decision to the University Council for Graduate Studies and Research.
    2. Accumulation of more than six hours of graduate credit with grades of C or below.
    3. Failure to accumulate the requisite number of points on the departmental comprehensive examinations. (See Section 4).
    4. Failure to satisfy the advisory committee on the final oral examination. (See Section 9).
CHEMISTRY (CHEM)

6001. Environmental Chemistry. (3).Chemical phenomena occurring in soil, atmospheric, and aquatic environments; consideration of natural resources and environment. Three lecture hours per week. PREREQUISITE: CHEM 3311.

6101. Inorganic Chemistry Laboratory. (1). Experimental techniques of inorganic synthesis and physical methods for characterization of inorganic and organometallic compounds. Three laboratory hours per week; $25 material fee. PREREQUISITE or COREQUISITE: CHEM 6111.

6111. Inorganic Chemistry. (3). Theoretical and applied inorganic chemistry, stressing the relationship of structure and bonding to the properties of elements and compounds; topics include introductory molecular orbital theory, coordination compounds and organometallics, ligand field theory, nonaqueous solvent systems, and reaction mechanisms. Three lecture hours per week. PREREQUISITE: CHEM 3412, or permission of the instructor

6180-99. Special Topics in Inorganic Chemistry. (1-3). Topics are varied and announced in online list of classes.

6211. Advanced Instrumental Analysis. (3). Study of topics in analytical instrumental analysis, including atomic spectroscopy, x-ray spectroscopy, UV-visible, luminescence, infrared, Raman, and nuclear magnetic resonance spectroscopy. Three lecture hours per week. PREREQUISITE: CHEM 3211 and CHEM 3412.

6280-99. Special Topics in Analytical Chemistry. (1-3). Topics are varied and announced in online course listings.

6311. Intermediate Organic Chemistry. (3). Further study of physical organic chemistry, spectrometric methods of identification of organic compounds, modern methods for organic synthesis, and natural products chemistry. PREREQUISITE: CHEM 3312 or permission of instructor.

6315. Organic Medicinal Chemistry. (3). Introduction to principles of medicinal chemistry; structure, synthesis, and biochemical mechanism of action of major drug classes. Three lecture hours per week. PREREQUISITE: CHEM 3312.

6380-99. Special Topics in Organic Chemistry. (1-3). Topics are varied and announced in Online course listings.

6411. Advanced Physical Chemistry. (3). Advanced topics in physical chemistry, including statistical mechanics and thermodynamics plus selected topics in kinetic theory of gases, condensed phases, and non-equilibrium processes. PREREQUISITE: CHEM 3412 or permission of instructor.

6415. Computational Chemistry. (3). Application of computers to problems in organic and inorganic chemistry; use of quantum chemistry codes to solve problems related to electronic, molecular, and vibrational structure.

6480-99. Special Topics in Physical Chemistry. (1-3). Topics are varied and announced in online course listings.

6501. Laboratory Techniques in Biochemistry. (2). (Same as MMCS 6503). Biochemical techniques, analysis and design strategies; emphasis on properties of proteins/enzymes, including binding, catalysis, kinetics, electron and proton transport processes of intermediate metabolism; purification, characterization, and assay of enzymes using chromatography, spectroscopy, electrophoresis. Six laboratory hours per week; $50 material fee. PREREQUISITE: CHEM 3302; PREREQUISITE OR COREQUISITE: CHEM 6511.

6511. Biochemistry I. (3). (Same as MMCS 6511). Chemistry of amino acids and proteins as related to their properties in biochemical systems; protein conformation studies; enzymology; coenzymes and their functions; importance of pH and bioenergetics in catalysis; protein and carbohydrate metabolism. Three lecture hours per week. PREREQUISITE: CHEM 3312 or equivalent.

6512. Biochemistry II. (3). (Same as MMCS 6512). A continuation of CHEM 6511; chemistry of lipids: metabolism, membrane formation and function in cell signaling mechanisms and sensory transduction; chemistry of nucleotides, DNA, and RNA; mechanisms of information storage and transmission; advanced treatment of enzyme kinetics. Three lecture hours per week.PREREQUISITE: CHEM 6511.

6580-99. Special Topics in Biochemistry. (1-3). Topics are varied and announced in online course listings.

6604. Instrumental Methods. (3). Analytical instrumental techniques including molecular spectroscopy, chromatography, atomic spectroscopy, and electrochemical analysis. One lecture, six laboratory hours per week; $25 material fee. PREREQUISITES: CHEM 3201, 3211, 3312 or permission of instructor.

7001-8001. Directed Research. (1-10). An original investigation undertaken with the supervision of a member of the graduate staff to be the basis of a contribution to the chemical literature. May be repeated for a maximum of 30 credit hours.

7100–09–8100-09. Special Topics in Inorganic Chemistry. (1-3). Lectures and conferences covering selected areas of current interest (including equilibrium, titrimetric, electroanalytical, and spectral methods, separation and radio-chemical techniques, microanalysis, statistics and data analysis, and electrode kinetics). May be repeated for a maximum of 12 credit hours. PREREQUISITE: Permission of instructor.

7111-8111. Systematic Inorganic Chemistry. (3). Survey of inorganic chemistry, including electronic structure, bonding, stereochemistry, symmetry, and the physical and chemical properties of the elements and their compounds. PREREQUISITE: CHEM 6111 or permission of instructor.

7200-09–8200-09. Special Topics in Analytical Chemistry. (1-3). Lectures and conferences covering selected areas of current interest (including equilibrium, titrimetric, electroanalytical, and spectral methods, separation and radio-chemical techniques, microanalysis, statistics and data analysis, and electrode kinetics). May be repeated for a maximum of 12 credit hours. PREREQUISITE: Permission of instructor.

7211-8211. Advanced Analytical Chemistry I. (3). Advanced treatment of topics in atomic and molecular spectroscopy, mass spectrometry, and surface analysis techniques. PREREQUISITE: CHEM 6211 or permission of instructor.

7212-8212. Advanced Analytical Chemistry II. (3). Advanced treatment of topics in electrochemical methods and separation techniques. PREREQUISITE: CHEM 6211 or permission of instructor.

7300-09–8300-8309. Special Topics in Organic Chemistry. (1-3). Lecture and conferences covering selected areas of current interest (including heterocyclic chemistry, organometallic compounds, organosulfur compounds, alkaloids, steroids, terpenes, photochemistry, biosynthesis, stereochemistry, carbohydrates, new synthetic methods, high polymers, and advanced physicalorganic chemistry). May be repeated for a maximum of 12 credit hours. PREREQUISITE: Permission of instructor.

7311-8311. Advanced Organic Chemistry. (3). Physical approach to organic reaction mechanisms; reactive intermediates, aromaticity, and pericyclic reactions; introduction to advanced spectroscopic techniques and synthetic philosophy. PREREQUISITE: CHEM 6311 or permission of instructor.

7312-8312. Synthetic Organic Chemistry. (3). Principles of synthesis of complex organic molecules. PREREQUISITE: CHEM 6311 or permission of instructor.

7314-8314. Heterocyclic Chemistry. (3). Reactions, synthesis, uses, and physical properties of heterocyclic compounds.

7400-09–8400-09. Special Topics in Physical Chemistry. (1-3). Lectures and conferences covering selected areas of current interest (including non-aqueous solutions, surface chemistry, x-ray crystallography, theoretical spectroscopy, nuclear chemistry, molecular structure of macromolecules, colloid chemistry, statistical thermodynamics, esr, and nmr). May be repeated for a maximum of 12 credit hours. PREREQUISITE: Permission of instructor.

7411-8411. Electronic Structure and Symmetry. (3). Basic quantum chemistry with applications to simple systems; group theory and its applications; molecular orbital theory including Huckel, SCF-LCAO-MO, and Qualitative MO methods. PREREQUISITE: CHEM 6411 or permission of instructor.

7414-8414. Advanced Quantum Chemistry. (3). Advanced treatment of topics in quantum chemistry with emphasis on electronic structure theories.

7500-09–8500-09. Special Topics in Biochemistry. (1-3). Lectures and conferences covering selected areas of current interest (including enzymology, protein and nucleic acid chemistry, physical chemistry of biochemical macromolecules, lipid, carbohydrate, and amino acid metabolism, biochemical energetics, and metabolic regulation). May be repeated for a maximum of 12 credit hours. PREREQUISITE: Permission of instructor.

†7600. Teaching Chemistry Laboratories. (2). Laboratory instruction emphasizing communication skills, laboratory conduct and safety, and evaluation of performance. Two laboratory hours per week.

7711-8711. Approximate Chemical Modeling Methods. (3). Development of approximate classical and quantum mechanical techniques for modeling chemical systems, molecular mechanics, semiempirical quantum mechanics. PREREQUISITE: CHEM 7411 or permission of instructor.

7712-8712. Computational Chemistry Programming. (3). Programming for chemical applications in chemistry, parallel programming methods, computational chemistry on high-performance computers. PREREQUISITE: CHEM 7411 or permission of instructor.

7713-8713. Advanced Solid State Physics and Chemistry. (3). Quantum mechanical treatment of electronic and vibrational states of metals, semiconductors and insulators, transport phenomena, superconductivity, physics of defects in solids. PREREQUISITE: CHEM 7411 or permission of instructor.

†7910-8910. Special Problems in Chemistry. (1-12). Individual investigation and report under the guidance of the student’s major advisor.

†7911. Presentation. (1). Preparation and presentation of a short talk or lecture based on a laboratory or library project. Topic chosen in consultation with advisor.

†7913-8913. Chemistry Seminar. (1). Formal meetings, presentation, and discussion of current topics of interest; students, faculty, and visiting scientists participate. Required of all regularly enrolled graduate students. A maximum of 4 credit hours from a combination of CHEM 6911, 7911, 8911, and 7-8913 may be counted toward the degree.

†7996. Thesis. (1-6).A An original investigation undertaken with the supervision of a member of the graduate staff. The investigation will be the basis of a thesis.

8500–09. Special Topics In Biochemistry. (1-3). Lectures and conferences covering selected areas of current interest (including enzymology, protein and nucleic acid chemistry, physical chemistry of biochemical macromolecules, lipid, carbohydrate, and amino acid metabolism, biochemical energetics, and metabolic regulation). May be repeated for a for a maximum of 12 credit hours. PREREQUISITE: Permission of instructor.

8700–09. Special Topics in Computational Chemistry. (1-3). Lectures and conferences covering selected areas of current interest (including artificial intelligence methods, molecular computing, semi-empirical quantum mechanics, combinatorial chemistry, computer-aided drug design, analysis of chemical databases, correlated methods, chemometrics, and parallel computing). May be repeated for a maximum of 12 credit hours. PREREQUISITE: Permission of instructor.

†8911. Advanced Presentation. (1). Preparation and presentation of one-hour lecture as regularly scheduled department seminar. Topic chosen in consultation with advisor.

†9000. Dissertation. (1-10).

†Grades of S, U, or IP will be given.